graduate student
Nizhniy Novgorod, Nizhny Novgorod, Russian Federation
Institute of Chemistry of Highly Pure Substances named after G.G. Devyatykh RAS
Nizhniy Novgorod, Nizhny Novgorod, Russian Federation
Institute of Chemistry of Highly Pure Substances named after G.G. Devyatykh RAS
Nizhniy Novgorod, Nizhny Novgorod, Russian Federation
Nizhniy Novgorod, Nizhny Novgorod, Russian Federation
Nizhniy Novgorod, Nizhny Novgorod, Russian Federation
544.35
Predstavleny rezul'taty rabot po polucheniyu obrazcov vysokochistogo tetrakis(triftorfosfin) nikelya. Metodami hromato-mass-spektrometrii i mass spektrometrii s induktivno svyazannoy plazmoy oharakterizovan primesnyy elementnyy i molekulyarnyy sostav ishodnogo i ochischennogo obrazcov. Pri provedenii processa pri skorosti peregonki 80 mkl/min i dole otbora 50% soderzhanie limitiruemyh primesey himicheskih elementov zheleza, medi i kobal'ta nahoditsya nizhe 0.01 ppm, soderzhanie PF3, CH2Cl2 i uglevodorodov na urovne n·10–3 ÷ n·10–5 mol.%.
tetrakis(triftorfosfin) nikelya, primes', distillyaciya, glubokaya ochistka, koefficient razdeleniya.
1. Makhatadze G.V., Schiller M., Bizzarro M. High precision nickel isotope measurements of early Solar System materials and the origin of nucleosynthetic disk variability. Geochim. Cosmochim. Acta, 2023, 343, 17-32. DOI:https://doi.org/10.1016/j.gca.2022.12.020.
2. Baranov V.Yu. Izotopy: svoystva, poluchenie, primenenie. M.: FIZMATLIT. 2005, 600 s.
3. Klein C.B., Costa M. Handbook on the Toxicology of Metals (Fifth Edition). Volume II: Specific Metals, 2022, 615–637.
4. Horasanov G.L., Ivanov A.P., Blohin A.I., Demin N.A. Vysokonikelevye stali, obednennye izotopom nikel'-58, dlya obolochek tvelov bystryh reaktorov. Vopr. atom. nauki i tehniki. Seriya: Materialovedenie i novye materialy, 2006, 2(67), 229-232.
5. Uhm Y.R., Choi B.G., Kim J.B., Jeong D.H., Son K.J. Study of a betavoltaic battery using electroplated nickel-63 on nickel foil as a power source. Nucl. Eng. Technol., 2016, 48(3), 773-777. DOI:https://doi.org/10.1016/j.net.2016.01.010.
6. Haritonov I.D., Mazgunova V.A., Babain V.A., Kostylev A.I., Merkushkin A.O., Shemuhin A.A., Balakshin Yu.V., Kozhemyako A.V., Kalmykov S.N., Magomedbekov E.P. CVD–tehnologiya proizvodstva atomnyh istochnikov na osnove Ni. Radiohimiya, 2018, 60(2), 143-147.
7. Baldohin Yu.V., Perfil'ev Yu.D., Kulikov L.A., Burnazyan M.A. Okislenie zheleza s raznym soderzhaniem izotopov. Vestnik Moskovskogo universiteta. Ser. 2. Himiya, 2015, 56(2), 91-97.
8. Asadulin R.S., Galkin D.E., Maslov A.E., Palienko A.A., Sovach V.P., Tuhvatullin V.K., Ushakov A.A. Patent RF № 2748573 S1, 2021.
9. Orlov A.A., Ushakov A.A., Sovach V.P. Razdelenie izotopov nikelya v processe zapolneniya kaskada gazovyh centrifug s razlichnym kolichestvom stupeney. TOHT, 2019, 53(2), 146-151. DOI:https://doi.org/10.1134/S0040357119020131.
10. Merkulov I.A., Tihomirov D.V., Obedin A.A., Zhabin A.Yu., Pareckova S.A., Tomarev A.N., Kudrina Yu.V., Grigor'eva V.A. Patent RF № 2650955 S1, 2018.
11. Sozin A.Yu., Chernova O.Yu., Sorochkina T.G., Troshin O.Yu., Bulanov A.D. Identifikaciya primesey v tetrakis(triftorfosfine) nikelya s ispol'zovaniem metoda hromato-mass-spektrometrii. AiK, 2018, 22(3), 253-258. DOI:https://doi.org/10.15826/analitika.2018.22.3.010.
12. Alekseev A.V., Yakimovich P.V., Kvachenok I.K. Opredelenie primesey v nikele metodom ISP-MS. Trudy VIAM, 2020, 2(86), 101-108. DOI:https://doi.org/10.18577/2307-6046-2020-0-2-101-108. URL: https://elibrary.ru/item.asp?id=42392009 (Data obrascheniya 29.01.2025).
13. Toporov Yu.G., Tarasov V.A., Romanov E.G., Kazakov L.L., Andreev O.I., Andreychuk N.N., Kornilov A.S., Rotmanov K.V. Poluchenie preparata nikelya–63 dlya istochnikov toka. Sbornik trudov AO GNC NIIAR, 2018, 2, 34-40.
14. Prusakov V.N., Petrov Yu.V., Simonov N.F., Hrustalev B.V. Patent SU 1061391, 1987.
15. Otopkova P.A., Potapov A.M., Suchkov A.I., Bulanov A.D., Lashkov A.Yu. Primenenie vnutrennego standarta pri izotopnom analize vysokoobogaschennogo kremniya–28 metodom mass-spektrometrii vysokogo razresheniya s induktivno svyazannoy plazmoy. AiK, 2021, 25(2), 98-109. DOI:https://doi.org/10.15826/analitika.2021.25.2.009.
16. Troshin O.Yu., Bulanov A.D., Chernova O.Yu. Liquid–Vapor Equilibria in the SiCl4–A (A = SiCl4–nFn (n = 1–4) Impurity) Systems. Inorg. Mater., 2018, 54, 840-843. DOI:https://doi.org/10.1134/S0020168518080162.
17. Devyatyh G.G., Elliev Yu.E. Glubokaya ochistka veschestv. Ucheb. posobie dlya vuzov. M.: «Vysshaya shkola». 1974, 160 s.
18. Kovalev I.D., Potapov A.M., Bulanov A.D. Izmerenie izotopnogo sostava izotopno-obogaschennogo kremniya i ego letuchih soedineniy metodom lazernoy mass-spektrometrii. Mass-spektrometriya, 2004, 1(1), 37-44.
