Ярославский государственный технический университет (Кафедра «Технология строительного производства»., Профессор)
Ярославль, Ярославская область, Россия
Национальный исследовательский университет «Высшая школа экономики»
Ярославский государственный технический университет
Ярославль, Ярославская область, Россия
УДК 665.334.83 Горчичное масло
On the basis of X-ray phase analysis data we identified the main structural elements of the solid phase of domestic aluminosilicates of different colours used for the purification of mustard oil by sorption. Also we defined these materials fractional and particle size distribution and realized 60-80% of their particles are 0.3-2.5 µm in size. The study reveals the important role of rock-forming fractions kaolinite and montmorillonite (up to 15%), high dispersion and moderately alkaline surface (pH of 1% aqueous dispersion 8.40-8.43) of aluminosilicate materials by LLC "PolyServis-M" (Moscow) in oil neutralization and bleaching. By the experiment results introduction of these domestic materials into mustard oil prevents its oxidation.
natural aluminosilicates, purification by sorption, mustard oil, free fatty acids, peroxides and wax compounds
1. Prokof'ev, V.Yu., Razgovorov, P.B. & Gordina, N.E. (2014) The adsorption of undesirable impurities from sunflower oil the granulated sorbents based on caolin clay, Int. J. Food Eng., 10(4), pp. 713-720. DOI:https://doi.org/10.1515/ijfe-2014-0103.
2. Shapkin, N.P., Razov, V.I., Khal’chenko, I.G., Shkuratov, A.L., Korochentsev, V.V. & Mayorov, V.I. (2016) Studies of natural kaolinite and its modified forms, J. Inorg. Chem., 61(11), pp. 1463-1471. DOI:https://doi.org/10.1134/S003602361611019X.
3. Tarasevich, U.I. (1988) Structure and Chemistry of Layered Silicates Surface. Kiyev: Nauk. Dumka (in Russian).
4. Bel'chinskaya, L.I., Khodosova, N.A., Novikova, L.A., Strel'nikova, O.Yu., Roessner, F., Petukhova, G.A. & Zhabin, A.V. (2016). Regulation of sorption processes in natural nanoporous aluminosilicates. 2. Determination of the ratio between active sites, Protect. Met. Phys. Chem. Surf., 52(4), pp. 599-606. DOI:https://doi.org/10.1134/S207020511604005.
5. Grevtsev, V.A. & Lygina, T.Z. (2010) Morphological and structural features of natural, activated and synthesized substances, Vestn. Kazan. technol. univ., 8, pp. 236-249 (in Russian).
6. Razgovorov, P.B., Ignatyev, A.A., Abramov, M.A. & Nagornov, R.S. (2020) Processing of raw aluminosilicates and subway construction dumps into composite sorbents for purification of water and oil-containing media, Smart Composites in Construction, 1(1), pp. 10-26. Available at: http://comincon.ru/index.php/tor/V1N1_2020. DOI:https://doi.org/10.52957/27821919_2020_1_10 (in Russian)
7. Efendiyev, A.A. (1994) On crystallisation of waxes in refined sunflower oil, Maslozhir. prom-st, 5-6, pp. 22-25 (in Russian).
8. Mikhailov, G.G., Lonzinger, T.M., Morozova, A.G., Skotnikov, V.A., Lonzinger, A.V. & Kutuev, A.A. (2015) Effect of composition and structure of natural aluminosilicate materials of Chelyabinsk region on sorption properties, Vestn. Yuzhno-Ural. gos. un-ta. Ser. Metallurgiya, 15(4), pp. 42-50. DOI:https://doi.org/10.14529/met150405 (in Russian).
9. Lygina, T.Z., Mikhailova, O.A., Khatsrinov, A.I. & Konyukhova, T.P. (2009) Technologies of chemical activation of inorganic natural mineral sorbents. Kazan: Kazan. gos. tekhnol. un-t (in Russian).
10. Sharafiev, D.R., Khatsrinov, A.I., Usmanov, N.V. & Kasymova, G.I. (2017) Modified natural adsorbents for refining vegetable oils, Vestn. Tekhnol. un-ta, 20(18), pp. 88-92 (in Russian).
11. Arfaoui, S., Frini-Srasra, N. & Srasra, E. (2009) Synthesis and characterization of hydroxy-chromium pillared bentonite, Surf. Eng. Appl. Electrochem., 45(3), pp. 239-245. DOIhttps://doi.org/10.3103/S1068375509030119.
12. Butman, M.F., Ovchinnikov, N.L., Arbuznikov, V.V. & Agafonov, A.V. (2012) Synthesis and properties of Al-pillarized montmorillonite of natural origin, Izv. Vuzov. Khimiya i khim. tekhnologiya, 55(8), pp. 73-77 (in Russian).
13. Ignatyev, A.A., Razgovorov, P.B., Nagornov, R.S., Politaeva, N.A., Mukhametova, L.R. & Ilyashenko, S.B. (2022) Composite Aluminosilicate Materials for Sorption Extraction of Impurity Substances of Vegetable Oils, Resources, 11(9), pp. 1-13.
14. Razgovov, P.B., Sitanov, S.V. & Kozlov, V.A. (2002) Study of interaction between some priming materials and the ester component of wax-like substances, Izv. vuzov. Khimiya i khim. tekhnologiya, 45(1), pp. 34-37 (in Russian).
