BIODEGRADABLE POLYMER COMPOSITES MATERIALS BASED ON SYNTHETIC POLYMERS AND NATURAL COMPONENTS
Abstract and keywords
Abstract (English):
The study aims to create biodegradable composite materials based on non-emulsion polymer latexes with natural fillers. The article provides an analysis of the current status of the issue on the methods of obtaining biodegradable polymer materials and methods for confirming their biodegradation under the influence of biotic and abiotic factors. The results of research on the development of a method for obtaining biodegradable polymer materials based on based on 1,4-cis-polyisoprene non-emulsion polymer latexes are presented. Using the method of determining the degree of decomposition of polymers under simulated composting conditions in laboratory tests, the ability of the created polymer composite products to biodegradation under the influence of soil microbiota has been proved. Stimulation of biodegradation processes occurs due to the natural fillers of wood flour and coffee oil cake introduced at the latex stage in the form of pre-prepared suspensions. The developed technology makes it possible to obtain, using the method of coagulant sedimentation, composite polymer thin-film materials with adjustable operating time, makes it possible to reduce the load on the environment after the disposal of used products by burying them into the soil at polygons. The obtained polymer composite materials can be used to obtain dipped articles, for example, gloves for household, pharmaceutical, and chemical purposes.

Keywords:
biodegradable, biodegradable composite polymer material, latex composition, dipped products, natural filler, synthetic polymer
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References

1. Pipiia L.K., Elkin A.G. Plastics processing: market assessment and prospects. Science abroad. Moscow, Izdatel’stvo Rossiiskoi akademii nauk, 2018. N 75. 33 p. (in Russian).

2. Navinchandra, G.S. Biodegradable and Biocompatible Polymer Composites: Processing, Properties and Applications / Navinchandra Gopal Shimpi. UK: Woodhead Publishing, 2017. 434 p.

3. Potapova E.V. The problem of recycling plasic waste. Izvestiya Baykal'sko gogosudarstvennogo universiteta, Irkutsk: Izdatel'stvo Baykal'skogo gosudarstvennogo universiteta, 2018. N 4. P. 535-544. DOIhttps://doi.org/10.17150/2500-2759.2018.28(4).

4. Fedotova O.B. The low-wasted technologies of packaging materials and development prospects. Aktual'nye voprosy molochnoi promyshlennosti, mezhotraslevye tekhnologii i sistemy upravleniia kachestvom, 2020. N 1. P. 560-565. DOIhttps://doi.org/10.37442/978-5-6043854-1-8-2020-1-560-565 (in Russian).

5. Dmitrienko V.P. et al. Assessment of environmental safety of thermoplastic materials based on linear polymers. Iindustrial Ecology. Moscow: Kompas, 2018. N 1. P. 52-59.

6. Patent RU № 2352597. Biodegradable granular polyolefin composition and method for its preparation / A.N., Ponomarev, published in 2009 (in Russian).

7. Volova T.G. Degradable Polyhydroxyalkanoates of Microbial Origin as a Technical Analog of Non-Degradable Polyolefines. Zhurnal Sibirskog ofederal'nog ouniversiteta. Biologiia. Krasnoiarsk: Izdatel’stvo Sibirskogo federal'nogo universiteta, 2015. N 2. P. 131-151. DOI:https://doi.org/10.17516/1997-1389-2015-8-2-131-151 (in Russian).

8. Vroman Isabelle, Tighzert Lan. Biodegradable polymers. Materials. Paris, 2009. N 2. P. 317-320.

9. Long Yu. Biodegradable polymer blends and composites from renewable resources. Hoboken: Jonh Wiley & Sons, 2009. 487 p.

10. Susheel K. Biodegradable green composites. Hoboken: Jonh Wiley & Sons, 2016. 380 p.

11. Pantiukhov P.V. Features of the structure and biodegradation of composite materials based on low density polyethylene and vegetable fillers. Moscow: Institut biokhimicheskoi fiziki Rossiiskoi akademii nauk, 2013. 128 p. (in Russian).

12. Rogovina S.Z. Biodegradable Polymer Composites Based on Synthetic and Natural Polymers of Various Classes. Vysokomolekuliarnye soedineniia. Moscow: Izdatel’stvo Instituta neftekhimiicheskogo sinteza, Rossiiskoi akademii nauk, 2016. N 1. P. 68-80. DOI:https://doi.org/10.17516/1997-1389-2015-8-2-131-151. (in Russian).

13. Elisa Barbosa de Brito, Lucas Galhardo Pimenta Tienne, Suellem Barbosa Cordeiro, Maria de Fátima Vieira Marques. Development of polypropylene composites with green coffee cake fibres subjected to water vapor explosion. Waste and biomass valorization. 2020. 13 p.

14. Buriak V.P. Biopolymers – present and future. Polimernye materialy. 2005. N. 12. P. 22-27 (in Russian).

15. Gotlib E.M., Golovanova K.V., Selekhova A.A. Ways of creating biodegradable polymeric materials and their production based on plasticized cellulose diacetates: monograph. Kazan': Kazanskii natsional'ny iissledovatel'ski i tekhnologicheskii universitet, 2011. 132 p. (in Russian).

16. Parmukhina E.L. Russian market of biodegradable packaging. Ekologicheskii vestnik Rossii. Moscow, 2011. P. 32-34 (in Russian).

17. Bazunova M.V., Prochukhan Iu.A. Methods of disposal of waste polymers. Vestnik Bashkirskogo universiteta. Ufa: Izdatel’stvo Bashkirskogo universiteta, 2008. N. 4. P. 875-885 (in Russian).

18. Suvorova A.I., Tiukova I.S. Recycling of polymers and creation of environmentally friendly polymeric materials. UMKD Ural'skogo gosudarstvennogo universiteta imeni Gor'kogo. Ekaterinburg 2008. 126 p. (in Russian).

19. Shtil'man M.I. Biodegradation of polymers. Zhurnal Sibirskogo federal'nog ouniversiteta. Biologiia. Krasnoiarsk: Izdatel’stvo Sibirskogo federal'nogo universiteta, 2015. N 2. P. 113-130. DOI:https://doi.org/10.17516/1997-1389-2015-8-2-113-130 (in Russian).

20. Belik E.S., Rudakova L.V., KulikovaIu V., Burmistrova M.V., Sliusar' N.N. Evaluation of the effectiveness of biodegradation of polymer composite materials. Vestnik Novosibirskogo gosudarstvennogo universiteta. Perm': Izdatel’stvo Novosibirskogo gosudarstvennogo universiteta, 2017. N 4. P. 111-118 (in Russian).

21. Ermolovich O.A., Makarevich A.V., Goncharova E.P., Vlasova G.M. Methods for assessing the biodegradability of polymeric materials. Biotekhnologiia. Moscow: Izdatel’stvo Gosudarstvennogo nauchno-issledovatel'skogo institute genetiki i selektsii promyshlennykh mikroorganizmov, 2005. N. 4. P. 47-54 (in Russian).

22. Glagoleva A.A., Smirnov V.F., Mochalova A.E., Smirnova L.A., Struchkova I.V., Bezukhova O.V. Changes in the physical and mechanical properties of compositions based on polyvinyl chloride and natural polymers in the process of microbiological damage. Vestnik Nizhegorodskogo universiteta imeni N.I. Lobachevskogo. Nizhniy Novgorod: Izdatel’stvo Nizhegorodskogo universiteta im. N.I. Lobachevskogo, 2013. N 5. P. 129-132 (in Russian).

23. Korotneva I.S., Mukhin A.S., Dmitriev K.E. Technology of obtaining biodegradable polymer films based on artificial latexes of synthetic polymers and natural fillers. Mezhdunarodnaia nauchno-prakticheskaia konferentsia «Obrazovanie, nauka i tekhnologii: aktual'nye voprosy, innovatsii i dostizheniia», Moscow, 2020. P. 279-282 (in Russian).

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