Yaroslavl, Yaroslavl, Russian Federation
from 01.01.1974 until now
Yaroslavl, Yaroslavl, Russian Federation
Yaroslavl, Yaroslavl, Russian Federation
UDC 66.092-977
V nastoyaschey rabote predstavleno kompleksnoe issledovanie vozmozhnosti i effektivnosti ispol'zovaniya tverdogo uglerodnogo ostatka (pirolizata), poluchennogo v processe nizkotemperaturnogo piroliza iznoshennyh avtomobil'nyh shin, v kachestve funkcional'nogo napolnitelya v recepturah rezinovyh smesey na osnove butadien-nitril'nyh kauchukov (BNK) marok BNKS-18AMN i BNKS-28AMN. Aktual'nost' raboty obuslovlena neobhodimost'yu resheniya ekologicheskoy problemy utilizacii polimernyh othodov i poiska ekonomicheski effektivnyh al'ternativ tradicionnym markam tehnicheskogo ugleroda, proizvodimym iz iskopaemogo syr'ya. V hode issledovaniya izucheny fiziko-himicheskie harakteristiki piroliznogo ugleroda, vklyuchaya ego dispersnost' i poverhnostnuyu aktivnost'. S primeneniem metodov vibroreometrii (MDR-2000), ravnovesnogo nabuhaniya i fiziko-mehanicheskih ispytaniy proveden sravnitel'nyy analiz kinetiki vulkanizacii i svoystv vulkanizatov, soderzhaschih pirolizat, po sravneniyu s etalonnymi smesyami, napolnennymi tehnicheskim uglerodom P 803, kaolinom i melom. Ustanovleno, chto pirolizat, obladaya specificheskoy himiey poverhnosti i vysokim soderzhaniem zol'noy frakcii (vklyuchaya oksid cinka i sul'fidy), okazyvaet suschestvennoe vliyanie na indukcionnyy period i skorost' vulkanizacii, vystupaya ne tol'ko kak napolnitel', no i kak vtorichnyy aktivator processa sshivaniya. Pokazano, chto pri uslovii optimizacii dispersnosti i korrektirovki vulkanizuyuschey gruppy vozmozhna effektivnaya zamena maloaktivnyh napolniteley i chastichnaya zamena poluaktivnogo tehugleroda bez kriticheskogo snizheniya ekspluatacionnyh harakteristik rezin, chto otkryvaet perspektivy dlya sozdaniya resursosberegayuschih tehnologiy v proizvodstve rezinotehnicheskih izdeliy.
pigment, oksid zheleza, othod, pigmentnye svoystva
1. Azihanov S.S., Petrov I.Ya., Ushakov K.Yu., Gorina V.Z., Bogomolov A.R. Piroliz rezinovoy kroshki, poluchennoy iz krupnogabaritnyh shin gruzovogo avtotransporta. ZhPH, 2022, 95(6),787-802. DOI:https://doi.org/10.31857/S0044461822060123. EDN: https://elibrary.ru/DLJNYD
2. Zaharyan E.M., Maksimov A.L. Piroliz poliamidsoderzhaschih materialov. Osobennosti processa i sostav produktov reakcii (obzor). ZhPH, 2022, 95(7), 811-844. DOI:https://doi.org/10.31857/S0044461822070015. EDN: https://elibrary.ru/DLPCBE
3. Zaharyan E.M., Maksimov A.L. Piroliz shin. Osobennosti processa i sostav produktov reakcii (obzor). ZhPH, 2021, 94(10-11), 1226-1264. DOI:https://doi.org/10.31857/S0044461821100017. EDN: https://elibrary.ru/DWTEIP
4. Banala D., Sabri Y., Roy Choudhury N., Parthasarathy R. Sustainable Valorisation of End of Life Tyres Through Pyrolysis Derived Recovered Carbon Black in Polymer Composites. Polymers, 2025, 17(20), 2771. DOI:https://doi.org/10.3390/polym17202771. EDN: https://elibrary.ru/XPHDTZ
5. Bridgestone Corporation, Michelin Group. Bridgestone and Michelin Publish recovered carbon black (rCB) joint technical white paper, 2023.
6. Buharkina T.V., Verzhichinskaya S.V., Tarhanova I.G., Konovalov A.V. Pererabotka tverdogo ostatka piroliza avtomobil'nyh shin. Izvestiya TPU. Inzhiniring georesursov, 2023, 334(8), 79-90. DOI:https://doi.org/10.18799/24131830/2023/8/4017. EDN: https://elibrary.ru/WZHTHN
7. Silva C.M., Maganinho C., Mendes A., Rocha J., Portugal I., Silva C.M., Recovered carbon black: A comprehensive review of activation, demineralization, and incorporation in rubber matrices. Carbon Resour. Convers., 2026, 9(1), 100334. DOI:https://doi.org/10.1016/j.crcon.2025.100334. EDN: https://elibrary.ru/FOBYZE
8. Koshelev M.M., Ul'yanov V.V., Harchuk S.E. Issledovaniya frakcionnogo sostava zhidkih produktov piroliza tverdyh organicheskih othodov v zhidkom svince. Teoret. osnovy him. tehnologii, 2021, 55(4), 489-495. DOI:https://doi.org/10.31857/S004035712103009X. EDN: https://elibrary.ru/MUPPPE
9. Bogdahn S., Koch E., Katrakova Krüger D., Malek C. Application of recovered Carbon Black (rCB) by Waste Tire Pyrolysis as an Alternative Filler in Elastomer Products. Adv. Mat. Sustain. Manuf., 2025, 2(2), 10008. DOI:https://doi.org/10.70322/amsm.2025.10008. EDN: https://elibrary.ru/RPGGIJ
10. Jovičić M., Bera O., Stojanov S., Pavličević J., Govedarica D., Bobinac I., Hollo B.B. Effects of recycled carbon black generated from waste rubber on the curing process and properties of new natural rubber composites. Polym. Bull., 2023, 80(5), 5047-5069. DOI:https://doi.org/10.1007/s00289-022-04307-x. EDN: https://elibrary.ru/SMWASH
11. Labaj I., Vršková J., Kopal I., Dubec A., Ondrušová D. Innovative Carbon Black Replacement in Rubber Compound: Impact of Pyrolytic Carbon Black and Energy-Gypsum By-Products on Vulcanization and Properties. Polymers, 2025, 17(22), 3080. DOI:https://doi.org/10.3390/polym17223080. EDN: https://elibrary.ru/DXVADE
12. Kol'cov N.I., Kos'yanov P.M. Issledovanie svoystv reziny na osnove butadien-nitril'nogo i galoidnyh kauchukov. Butlerovskie soobscheniya, 2023, 74(4), 77-80. DOI:https://doi.org/10.37952/ROI-jbc-01/23-74-4-77. EDN: https://elibrary.ru/WGBWQC
13. Horoshavina Yu.V., Zabelina A.N., Glushak M.I., Ramsh A.S., Kurlyand S.K. Issledovanie metodom dielektricheskoy spektroskopii modifikacii klasternyh struktur butadien nitril'nyh kauchukov i ih vulkanizatov. Zhurnal fizicheskoy himii, 2021, 95(12), 1876-1881. DOI:https://doi.org/10.31857/S0044453721120116. EDN: https://elibrary.ru/OMEERO
14. Cherezova E.N., Galihanov M.F., Karaseva Yu.S., Nakyp A.M. Vliyanie sostava rezin, napolnennyh karbokismetilcellyulozoy, na ih svoystva. ZhPH, 2023, 96(4), 391-396. DOI:https://doi.org/10.31857/S0044461823040096. EDN: https://elibrary.ru/OFYVZU
15. Trusov K.I., Osipenok E.M., Yusevich A.I. Vliyanie termicheskoy obrabotki tyazheloy smoly piroliza na vyhod i kachestvo naftalina. ZhPH, 2022, 95(5), 646-655. DOI:https://doi.org/10.31857/S0044461822050115. EDN: https://elibrary.ru/DJJOMV
16. GOST 7885-86. Uglerod tehnicheskiy dlya proizvodstva reziny. Tehnicheskie usloviya. – Vved. 1987 01 01. – M.: Standartinform, 2007.
17. Solov'ev M.E., Kablov V.F., Baldaev S.L., Fedorova M.O. Modelirovanie kinetiki termodestrukcii rezin pri pirolize rezinovyh othodov. Ot himii k tehnologii shag za shagom, 2023, 4(1), 70-85. DOI:https://doi.org/10.52957/27821900_2023_01_70. EDN: https://elibrary.ru/GPNCZG
18. Shadrinov N.V., Haldeeva A.R., Fedorov A.L., Kondakov M.N., Sokolova M.D. Vliyanie vulkanizuyuschey sistemy na strukturu i svoystva polimerelastomernyh kompozitnyh materialov. Vysokomol. soedineniya. Ser. A, 2023, 65(5), 374-383. DOI:https://doi.org/10.31857/S2308112023600096. EDN: https://elibrary.ru/DDBUZC
19. GOST R 54547-2011. Smesi rezinovye. Opredelenie vulkanizacionnyh harakteristik s ispol'zovaniem bezrotornyh reometrov. – Vved. 2013-07-01. – M.: Standartinform, 2012.
20. El Zayat M.M., Yousif N.M., El Basheer T.M., Mounir R. Synergistic influence of carbon black and montmorillonite nano clay on mechanical, electrical, and acoustic properties of nitrile butadiene rubber nanocomposites via gamma radiation. Radiochim. Acta, 2025, 113(9), 725-737. DOI:https://doi.org/10.1515/ract-2024-0367. EDN: https://elibrary.ru/ICDTLG
21. Yu S., Tang Z., Wang D., Wu S., Chen F., Guo B., Zhang L. Reviving recovered carbon black as a reinforcement for natural rubber by utilizing acylhydrazine functionalized polysulfide as an intelligent interfacial modifier. Polym. Chem., 2025, 16, 1949-1960. DOI:https://doi.org/10.1039/D5PY00111K. EDN: https://elibrary.ru/QVMMXC
22. GOST 270-75. Rezina. Metod opredeleniya uprugoprochnostnyh svoystv pri rastyazhenii. – Vved. 1977 01 01. – M. : IPK Izdatel'stvo standartov, 2002.
23. GOST 263-75. Rezina. Metod opredeleniya tverdosti po Shoru A. – Vved. 1977-01-01. – M.: Izdatel'stvo standartov, 1989.
24. GOST 9.030-74. Edinaya sistema zaschity ot korrozii i stareniya. Reziny. Metody ispytaniy na stoykost' v nenapryazhennom sostoyanii k vozdeystviyu zhidkih agressivnyh sred. – Vved. 1975-07-01. – M.: Izdatel'stvo standartov, 1975.
25. Solov'ev M.E., Solov'ev E.M. Patent RF 2608893, 2017.
26. Solov'ev M.E., Andropov V.A., Solov'ev E.M. Patent RF 166453 B29B 17/00, 2016.
27. Solov'ev M.E. Solov'ev E.M., Nikolaev S.V., Durosov S.M. Patent RF 2592905 B02C 4/02, 2016.
