PROCESSING OF RAW ALUMINOSILICATES AND SUBWAY CONSTRUCTION DUMPS INTO COMPOSITE SORBENTS FOR PURIFICATION OF WATER AND OIL-CONTAINING MEDIA
Abstract and keywords
Abstract (English):
The study establishes that natural raw aluminosilicate and dumps from Moscow subway construction can be used as composite sorbents for treatment of oil containing media after calcination to 350-400 °C and further modification. To do this, we have analyzed the works of Russian and foreign scientists and authors’ experimental studies of physical and chemical properties of these materials. The activity of materials is determined by particle size, porosity, and pore volume distribution, as well as concentration of additional Lewis and Bronsted centers on the surface as a result of acid-alkali treatment. These centers can be used to sorb impurities in aqueous and oily media depending on the polarity of the adsorbate molecules. The study revealed promising directions of research into obtaining composite sorbents by treating raw aluminosilicate raw materials and construction clay waste mechanically and chemically as well as using composites with activated charcoal. The study also elaborates on using extruded composites to simplify technological cycle of purification of oil-containing media. It shows that the regenerating ability of the obtained sorbents is determined in many respects by the alkaline agents present in them. It also includes a list of physical-chemical methods for complex research of media purifica-tion quality after contact and subsequent separation of the phases by filtration.

Keywords:
natural aluminosilicate raw materials, underground construction dumps, modification, composite sorbents, montmorillonite, kaolinite, water and oil-containing media
Text
Publication text (PDF): Read Download
References

1. Prokof'ev V.Yu., Razgovorov P.B., Gordina N.E. The ad-sorption of undesirable impurities from sunflower oil the granulated sorbents based on caolin clay. Int. J. Food Eng. 2014. V. 10. N 4. P. 713-720.

2. Razgovorov P.B., Sitanov S.V., Kozlov V.A. Investigation of interaction of some priming (fuse) materials and ester com-ponent of wax-like compounds. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2002. T. 45. N. 1. P. 34-37 (in Rus-sian).

3. Razgovorov P.B., Sitanov S.V. Express analysis of waxes in vegetable oils. Maslozhir. promyshl. 2009. N 3. P. 21-23 (in Russian).

4. Razgovorov P.B., Gorshkov V.K. Processing equipment of industry: calculations in oil and fat productions: tutorial. Ivanovo: ISUCT. 2009. 48 p. (in Russian).

5. Lygina T.Z., Mikhailova O.A. Physico-chemical and adsorption methods for studying inorganic natural mineral sorbents: tutorial. Kazan: KSTU. 2009. 80 p. (in Russian).

6. Razgovorov P.B., Nagornov R.S., Razgovorova M.P. Utilization of blue clay for separation of impurities from linseed oil.Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2014. V. 57. N 12. P. 72-75 (in Russian).

7. Lygina T.Z., Mikhailova O.A., Khatsrinov A.I., Konyukhova T.P. Technology of chemical activation of inorganic natural mineral sorbents. Kazan: KSTU. 2009. 120 p. (in Russian).

8. Lukomskiy Yu.Ya., Gorshkov V.K., Razgovorov P.B. Galvanic and paint coatings on aluminum and its alloys. Ivanovo: ISUCT. 2019. 239 p. (in Russian).

9. Bel'chinskaya L.I., Khodosova N.A., Novikova L.A., Strel'nikova O.Yu., Roessner F., Petukhova G.A., Zhabin A.V. Regulation of sorption processes in natural nanoporous aluminosilicates. 2. Determination of the ratio bitween active sites. Protect. Met. Phys. Chem. Surf. 2016. V. 52. N 4. P. 599-606.

10. Grevtsev V.A., Lygina T.Z. Morphological and structural features of natural, activated and synthesized substances. 2010. Vestn. Kazan.technol. Univer. 2010. No. 8. P. 236-249 (in Russian).

11. Goldberg V.M., Skvortsov N.P. Permeability and filtration in clays. M.: Nedra. 1986. 160 p. (in Russian).

12. Shapkin N.P., Razov V.I., Khal’chenko I.G., Shkuratov A.L., Korochentsev V.V., Mayorov V.I.Studies of natural kaolinite and its modified forms. J. Inorg. Chem. 2016. V. 61. N 11. P. 1463-1471.

13. Mikhailov G.G., LonzingerT.M., Morozova A.G., Skot-nikov V.A., Lonzinger A.V., Kutuev A.A. Influence of composition and structure of natural aluminosilicate materials of the Chelyabinsk region their sorption properties. Vestn. Yu-zhn.-Ural. gos. Univer. Ser. Metallurgiya. 2015. V. 15. N. 4. P. 42-50 (in Russian).

14. Sharafiev D.R., Hatsrinov A.I., Usmanov N.V., Kasymova G.I. Modified natural adsorbents for refining of vegetable oils. Vestn. technol.Univer. 2017. V. 20. N. 18. P. 88-92 (in Russian).

15. Sabitov A.A., Ruselik E.S., Trofimova F.A., Teterin A.N. Russian behtonite: the curreht state and prospects for the development of the resource base. Mineral resources of Russia. Economics and management. 2010. N. 5. P. 8-17 (in Russian). 16. Khodosova N.A., Pryazhentseva K.A., Zotova S.A. Eval-uation of sorption capacity of natural and acid-activated alumosilicates of various structures. Sci. Bullet. Voronezh. State Univer. Arch. Civil Eng. Ser. High technol. Ecology. 2016. N. 1. P. 130-136 (in Russian).

16. Hodosova N.A., Pryazhenceva K.A., Zotova S.A. Ocenka sorbcionnoy sposobnosti prirodnyh i kislotno-aktivirovannyh alyumosilikatov razlichnoy struktury. Nauch. vestn. Voronezh. gos. arhitekt.-stroit. un-ta. Ser. Vysokie tehnologii. Ekologiya. 2016. № 1. S. 130-136.

17. Sapronova Zh.A., Gomez M.Zh., Sverguzova S.V. Ultraviolet activation of natural clays of Angolan deposits to increase their sorption activity in water treatment processes. Belgorod: BSTU. 2015. 157 p. (in Russian).

18. Tserenkhand B., Bolmaa G., Bayaraa B. Chemical and mineralogical composition of some clays in uvsnuuraimak (Mongolia). Bullet. Buryat State Univer. 2014. V. 3. P. 17-20 (in Russian).

19. Trezza M.A., Tironi A., Irassar E.F. Thermal Activation of Two Complex Clays (Kaolinite-PyrophilliteIllite) from Tandilia System, Buenos Aires, Argentina. In book: Calcined Clays for Sustainable Concrete. 2018. P. 469-474

20. Ryazanov M.A., Dudkin B.N. Acid-Base Properties of γ-Al2O3 Suspension Studied by pK Spectroscopy. Colloid J. 2003. V. 65. No 6. P. 761-766.

21. Razgovorov P.B., Nagornov R.S., Razgovorova M.P., Grechin O.V. Regulation of aluminosilicate materials acid-base properties for action on purification degree of olive oil. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2015. V. 58. N 10. P. 58-63 (in Russian).

22. Prokof'ev V.Yu., Razgovorov P.B. Phusical and chemical processes occurring when introducing of kaolin clays in vege-table oils. Khimiya rastitel'nogo syr'ya. 2010. N. 2. P. 159-164 (in Russian).

23. Shcherbakov A.A., Klepikov M.S., Solodkii N.F., Serikov A.S., Rukavishnikov V.V., Zhestkov V.M., Belevitin V.A. Chemical composition of the conditioned and nonconditioned Nigneuvelyskayas clay Chelyabinsk region. Bashkir. Chem. J. 2011. V. 18. N. 4. P. 236-239 (in Russian).

24. Lamberov A.A., Sitnikova E.Yu., Abdulganeeva A.Sh. Influence of the composition and structure of kaolinite clays on the conditions of transition of kaolinite to metacaolinite. Vestn. Kazan. technol. Univer. 2011. N. 7. P. 17-23 (in Rus-sian).

25. Chelly M., Srasra E. Physico-cemical characterization and thermal behavior of two Tunisians kaolins. Surf. Engin. Appl. Electrochem.2009. V. 45. N 1. P. 47-55.

26. Kanygina O.N., Kravtzova O.S., Chetverikova A.G., Ku-leeva A.H., Salnikova E.V., Volkov E.V., Shambulatova A.T. Fractional structures of brick clays from Orenburzhye. Vestn. Omsk. gos. Univer. 2011. V. 131.N 12. P. 396-398 (in Russian).

27. Tardy Y., Fritz B. An ideal solid solution model for calculating solubility of clay minerals. Clay Minerals.1981. V. 16. N 4. P. 361-373.

28. Prokof'ev V.Yu., Razgovorov P.B., Smirnov K.V., Ilyin A.P., Shushkina E.A. Flax oil purification on a modified white clay. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2007. V. 50. N 6. P. 65-69 (in Russian).

29. Kumar P., Jasra R.V., Bhat T.S.G. Evolution of Porosity and Surface Acidity in Montmorillonite Clay on Acid.Indian Eng. Chem. Res. 1995. N 34. P. 1440-1448.

30. Nagornov R.S., Razgovorov P.B., Lepilova A.M., Stroga-nova Y.I., Smirnov P.R., Kochetkov S.P. Gentle activation of polymineral sorbent and its influence on the process of cleaning oil-containing media from impurity ingredients. Izv. Vyssh. Uchebn. Zaved. Khim. Khim.Tekhnol. 2017. V. 60. N 8. P. 53-59 (in Russian).

31. Stroganov V.F., Amelchenko M.O. Study the effect of acid activated kaolin on the properties of waterborne coatings. Izv. KGASU. 2014. V. 30. N 4. P. 284-290 (in Russian). 33. Yahaya S., Jikan S.S., Badarulzaman N.A., Adamu A.D. Effects of Acid Treatment on the SEM-EDX Character-istics of Kaolin Clay.Path Sci. 2017. V.9. N 3. P. 4001-4002.

32. Ming H., Spark K.M. Radio Frequency Plasma-Induced Hydrogen Bonding on Kaolinite. J. Phys. Chem.2003. V. 107. N 3. P. 694-702. 35. Kurtukova L.V., Somin V.A., Komarova L.F. Changing the properties of bentonite clays under the action of various activators. Polzunovskiy Vestn. 2013. N. 1. P. 287-289 (in Rus-sian). 36. Meldeshov A.A. Adsorption descriptions of the activated Keles clay. Bullet. of Kazakh. Acad. transport and communi-cat. nam. M. Tynyshpaeva. 2017. V. 101. N 2. P. 48-52 (in Russian).

33. Mel'deshov A.A. Adsorbcionnye harakteristiki aktivirovannoy Kelesskoy gliny. Vestn. Kazah. Akad. transporta i kommunikaciy im. M. Tynyshpaeva. 2017. T. 101. № 2. S. 48-52.

34. Vorsina L.A., Grigor'eva T.F., Devyatkina E.T., Vosmer-ikov S.V., Udalova T.A., Lyakhov N.Z. Interaction of organic acids with silicates in the cource of joint mechanical activation. J. Appl. Chem. 2017. V. 90. N 3. P. 334-341.

35. Tuchkova A.I., Tyupina E.A., Rakhimov M.G. Influence of alkaline activation of clay minerals on their sorption ability to extract Cs-137 from spent oil. Usp. Khim. Khim. Tekhnol. 2012. V. XXVI. N 6. P. 92-95 (in Russian).

36. Bel'chinskaya L.I., Voishcheva O.V., Khokhlov V.Y., Lu T.Y., Zhabin A.V., Petukhova G.A. The influence of alkaline treatment on the chemical composition and adsorption-structural characteristics of mineral nanoporous sorbent M45K20. Protect. Met. Phys. Chem.Surf. 2012. V. 48. No 3. P. 322-327.

37. Zhdanov S.P., Egorova E.N. Chemistry of zeolites. L.: Nau-ka. 1968. 158 p. (in Russian).

38. Lebedev M., Zhernovsky I., Strokova V. Effect of Heat Treatment on Phase Compositions of Clay Aluminosilicates. Nanotechnology in Construction. 2015. P. 123-129.

39. Trofimova F.A., Gubaidullina A.M., Demidova M.I. The degree of dispersion as one of the criteria for the quality of natural aluminosilicates. Vestn. Kazan. tekhnol. Univer. 2010. N 6. P. 218-224 (in Russian).

40. Kalinkin A.M., Kalinkina E.V., Zalkind O.A. Mechano-sorption of carbon dioxide by Ca- and Mg-containing silicates and alumosilicates. Sorption of CO2 and structure-related chemical changes. Colloid J. 2009. V. 71. No 2. P. 185-192.

41. Zulumyan N.H., Papakhchyan L.R., Isahakyan A.R., Beglaryan H.A., Aloyan S.G. Effect of mechanical treatment on the silicate lattice of kaolinite. J. Phys. Chem.2012. V. 86. No 12. P. 1887-1891.

42. Butman M.F., Ovchinnikov N.L., Arbuznikov V.V., Agafonov A.V. Synthesis andproperties of Al-pillared montmorillonite of natural origin. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2012. V. 55. N 8. P. 73-77 (in Russian).

43. Akkari R., Srasra E. Polybenzidine-montmorillonite nano-composites: synthesis via a mechanochemical intercalation method. Surf. Eng. Appl. Electrochem. 2010. V. 46. N 4. P. 361-366.

44. Arfaoui S., Frini-Srasra N., Srasra E. Synthesis and characterization of hydroxy-chromium pillared bentonite. Surf. Eng. Appl. Electrochem. 2009. V. 45.N 3. P. 239-245.

45. Hlihor R. M., Gavrilescu M. Removal of some environmentally relevant heavy metals using low-cost natural sorbents. Environ. Eng. and Manag. J. 2009. V. 2. N 8. P. 353-372.

46. Mulyutin V.V., Gelis V.M., Nekrasova N.A., Kononenko O.A., Vezentsev A.I., Volovicheva N.A., Korol'kova S.V. Sorption of Cs, Sr, U, and Pu radionuclides on natural and modified clays. Radiochem. 2012. V. 54. N 1. P. 75-78 (in Russian).

47. Ayari F., Srasra E., Trabelsi-Ayad M. Effect of exchangea-ble cations on the physicochemical properties of smectite. Surf. Eng. Appl. Electrochem. 2007. V. 43. I. 5. P. 369-378.

48. Teng M.-Y. Lin S.-H. Removal of basic dye from water onto pristine and HCl-activated montmorillonite in fixed beds. De-salination. 2006. V. 194. I. 1-3. P. 156-165.

49. Timofeev K.L., Maltsev G.I., Sviridov A.V. Indium extraction from solutions with modified aluminosilicates. Izv. Vyssh.Uchebn. Zaved. Khim. Khim. Tekhnol. 2016. V. 59. N 7. P. 35-41 (in Russian).

50. PatelM.A., Kar A.S., Kumar S., Tomar B.S. Effect of phos-phate on sorption of Eu (III) by montmorillonite. J. Radio-anal. Nucl. Chem.2017. V. 313. N 3. P. 537-545.

51. Zhou Q., Pan G., Shen W. Enhanced sorption of perfluorooctane sulfonate and Cr (VI) on organomontmorillonite: Influence of solution pH and uptake mechanism. Adsorption. 2013. V. 19. N 2-4. P. 709-715.

52. Goyal S., Goyal G.K. Nanotechnology in food packaging – a critical review. Rus. J. Agricult. and Soc.-Econ. Sci. 2012. V. 10. N 10. P.10-24.

53. Mattia C.D., Paradiso V.M., Andrich L., Giarnetti M., Caponio F., Pittia P. Effect of Olive Oil Phenolic Compounds and Maltodextrins on the Physical Properties and Oxidative Stability of Olive Oil O/W Emulsions. Food Biophys. 2014. V. 9. N 4. P. 396-405.

54. Aladedunye F.A., Przybylsk R. Frying Performance of Canola Oil Triacylglycerides as Affected by Vegetable Oils Minor Components. J. Amer. Oil Chem. Soc. 2012. V. 89. N 1. P. 41-53.

55. Razgovorov P.B. Extraction of waxes from oil-containing systems in the presence of sorbents and emulsifiers. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2006. V. 49. N 5. P. 3-10 (in Russian).

56. Prokof'ev V.Yu., Razgovorov P.B., Razgovorova M.P. Studying of waxes crystal formation process in vegetable oils in the presence of primed mineral additives. Khimiya ras-titel’nogo syr'ya. 2013. N 2. P. 207-212 (in Russian).

57. Gerasimenko E.O. Patent RU N 2174993. 2001.

58. Nasedkin V.V., Boeva N.M., Garbuzova I.A., Koval'chuk M.V., Vasil'iev A.L. The crystal structure and chemistry of several palygorskite samples with different geneses. Crystallogr. Reports. 2009. V. 54. N 5. P. 884-900.

59. Sabitov A.A., Galiakhmetov R.G., Trofimova F.A., Ruselik E.S., Nikolaeva L.M. Sepiolite clays of Meteger origin (Republic of Sakha (Yakutia)) – a new type of nonmetallic raw material in Russia. Razvedka i okhrana nedr. 2015. N. 4. P. 29-34 (in Russian).

60. Singer A., Galan E. Develoopments in Palygorskite-Sepiolite Research. A New Outlook of these Nanomaterials. Elsevier: Oxford-Amsterdam. 2011. 520 p.

61. Ismatov S.Sh., Khudoerov D.U. Effects of local adsorbents for cleaning cotton oil and products of its processing. Vopr. nauki i obrazovaniya. 2017. N 1.P. 45-46 (in Russian).

62. Hechi E., Amor O.B., Srasra E., Zargouni F. Physico-chemical characterization of acid-activated clay: its industrial application in the clarification of vegetable oils. Surf. Eng. Appl. Electrochem. 2009. V. 45. N 2. P. 140-144.

63. Laatikainen M., Srithammavut W., Toukoniitty B., Turunen I., Sainio T. Phospholipid adsorption from vegetable oils on acid-activated sepiolite. Adsorption. 2015. V. 21. N 5. P. 409-417. 67. Essid K., Jahwach-Rabai W., Trabelsi M., Frikha M.H. Sterolic Composition of Neutralized Oils Bleached with Clays Activated with Ultrasound. Iran. J. Sci. Technol. Transact. A: Sci. 2016. V. 40. N 3. P. 183-189.

64. Su H., Wang X., Kim Y.G., Kim S.B., Seo Y.-G., Kim J.S., Kim C.-J. Optimization of decoloring conditions of crude fatty acids recovered from crude glycerol by acid-activated clay using response surface method. Korean J. Chem. Eng. 2014. V. 31. N 11. P. 2070-2076.

65. Hechi A.E., Srasra E., Zargouni F. Physico-chemical characterization of acid-activated clay: its industrial application in the clarification of vegetable oils. Mater. Sci. Ind. J. 2007. V. 3. I. 3. P. 146-149.

66. Chakroun S., Herchi M., Mechti W., Gaied M.E. Acid activation of upper Eocene Ca-bentonite for soybean oil clari-fication.Environ. Sci. Pollut. Res. Int. 2017. V. 24. N 28. P. 22557-22569.

67. Yoon S.H. Optimization of the refining process and oxida-tive stability of chufa (Cyperusesculentus L.) oil for edible purposes. Food Sci. Biotechn. 2016.V. 25. N 1. P. 85-90.

68. Paranuk A.A., Khrisonidi V.A., Ponomareva G.V., Guchetl Z.Ch., Lysenko Yu.A. Development of oil drying installation on zeolites. Usp. sovrem. nauki. 2017. V. 2. N. 6. P. 169-173 (in Russian).

69. Suvanova F.U. Application of adsorbents for processing cottonseed oil and miscella. Aktual. nauchn. issled. v sovrem. mire. 2016. V. 13. N. 5-2. P. 130-134 (in Russian).

70. Muslimov B.B., Ismatov S.Sh., SharifovaN.A. Selected technologies for cottonseed oilrefining. Vopr. nauki i obrazovaniya. 2017. N. 5 (6). P. 11-13 (in Russian).

71. Prokof'ev V.Yu., Razgovorov P.B., Smirnov K.V., Shush-kina E.A., Il'in A.P. Extru-sion molding of kaolin sorbents. Glass and Ceramics. 2007. V. 64. N 7-8. P. 287-290.

72. Zakharov O.N., Prokof'ev V.Yu., Razgovorov P.B., Razi-na Zh.V. Sorbent forming from modified clay of Ivanovo re-gion field. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2009. V. 52. N 2. P. 87-90 (in Russian).

73. Zakharov Yu.A., Motygullin E.K , Gil’mutdinov A.Kh. Direct determination of phosphorus in vegetable oils by elec-trothermal atomic absorption spectrometry. J. Anal. Chem. 2000. V. 55. N 7. P. 649-652.

74. Vezentzev A.I., Kormosh E.V., Zdorenko N.M., Goldovskaja-Peristaja L.F. Adsorption properties of enrichment products of natural montmorilloniteclays. Nauch. vedomosti. Ser. Estestv. nauki. 2011. N. 9. V. 15. P. 103-109.

Login or Create
* Forgot password?